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101.
水敏现象在石油、岩土和环境工程等领域广泛存在。有效地控制水敏现象的发生,不仅具有科学意义,还有一定的经济价值。本文在广泛查阅国内外研究成果的基础上,总结了水敏性在石油、岩土和环境工程方面应用的研究进展,并在此基础上提出了水敏性研究的发展方向。 相似文献
102.
新型白云岩珠核的研究 总被引:2,自引:0,他引:2
筛选天然白云岩为原料,采用机械磨削和表面处理等工艺,制成新型珠核。这种珠核物化性质与现有贝、蚌壳珠核相近,具有颜色白、光泽强、外形圆和价格低廉等特点。研制和开发新型白云岩珠核,既能保护生物资源和生态环境,又能满足今后珍珠产业发展的需求。 相似文献
103.
Precise/ Small Sample Size Determinations of Lithium Isotopic Compositions of Geological Reference Materials and Modern Seawater by MC-ICP-MS 总被引:6,自引:1,他引:6
Alistair B. Jeffcoate Tim Elliott Alex Thomas Claudia Bouman 《Geostandards and Geoanalytical Research》2004,28(1):161-172
The Li isotope ratios of four international rock reference materials, USGS BHVO-2, GSJ JB-2, JG-2, JA-1 and modern seawater (Mediterranean, Pacific and North Atlantic) were determined using multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). These reference materials of natural samples were chosen to span a considerable range in Li isotope ratios and cover several different matrices in order to provide a useful benchmark for future studies. Our new analytical technique achieves significantly higher precision and reproducibility (< ± O.3%o 2s) than previous methods, with the additional advantage of requiring very low sample masses of ca . 2 ng of Li. 相似文献
104.
M. Roy-Barman C. Jeandel M. Souhaut M. Rutgers van der Loeff I. Voege N. Leblond R. Freydier 《Earth and Planetary Science Letters》2005,240(3-4):681-693
230Th, 232Th and 234Th were analyzed in sinking particles collected by moored and drifting sediment traps in the NE Atlantic Ocean (POMME experiment) in order to constrain the phase(s) carrying Th isotopes in the water column. It reveals a contrasted behaviour between 234Th and 230Th. 234Th is correlated to the particulate organic carbon suggesting that it is primarily scavenged by organic compounds in the surface waters. 230Thxs is correlated with Mn, Ba and the lithogenic fraction that are enriched in small suspended particles and incorporated in the sinking particulate flux throughout the water column. The lack of correlation between 230Thxs and CaCO3 or biogenic silica (bSi) indicates that CaCO3 and bSi are not responsible for 230Th scavenging in the deep waters of this oceanic region. 230Th is generally correlated with the lithogenic content of the trapped material but this correlation disappears in winter during strong atmospheric dust inputs suggesting that lithogenic matter is not directly responsible for 230Th scavenging in the deep waters or that sufficient time is required to achieve particle–solution equilibration. MnO2 could be the prevalent 230Thxs-bearing phase. The narrow range of Kd_MnO2Th obtained for very contrasted oceanic environments supports a global control of 230Thxs scavenging by MnO2 and raises the possibility that the 230Th–231Pa fractionation is controlled by the amount of colloidal MnO2 in seawater. 相似文献
105.
In this paper, the application of a homemade Nation and Co(Salen) modified platinum microelectrode and an ISO-NOPMC microsensor (World Precision Instruments, USA ) to measure nitric oxide in natural seawater is reported. These two microelectrodes are suitable for the measurement. In natural seawater, the sensitivity and stability of the ISO-NOPMC microsensor are higher than that of the homemade Nation and Co(Salen) modified platinum microelectrode. 相似文献
106.
Early-indicator signals of groundwater contamination: the case of seawater encroachment 总被引:4,自引:0,他引:4
An early indication of groundwater contamination occurs when pollutant concentrations start to fluctuate and exceed background
values of ambient fresh groundwater. An analysis of a characteristic situation of this type uses data from Israel's coastal
phreatic granular aquifer. The pollutant is generally seawater, and the contamination process involves replacement of freshwater
by encroaching sea- or other saltwater, a process augmented by human activity. The contamination process involves three stages:
(1) groundwater composition remains relatively stable with small salinity content; (2) small salinity changes are perceptible
with reversible fluctuations; and (3) salinity concentration increases at a sharply higher rate. The second stage is a useful
early-indicator signal of contamination. Early-indicator signals of groundwater pollutant concentrations involve "minor" fluctuations
in water chemistry at the advent of the contamination process. The intensity and magnitude of such a salinization/pollution
process at any given location depends upon lithologic matrix, aquifer heterogeneity, and resultant flow domain characteristics,
as well as contaminant properties. If such "signs" are detected at a sufficiently early stage, appropriate management steps
may be taken to rectify further seawater and/or saltwater encroachment.
Received: 23 July 1996 · Accepted: 25 June 1997 相似文献
107.
杨瑞东 《沉积与特提斯地质》1998,18(1):43-47
本文以沟鞭藻生态为基础,结合我国东部第三纪盆地的地球化学、古生物、岩相古地理、区域地质和全球海平面变化,论证东部含油气盆地在第三纪时不存在海水侵进。出现有“海相”沟鞭藻、有孔虫和钙质超微化石是由于当时湖泊咸化及富养料造成的。同时认为沟鞭藻是广盐性生物,其最适应于半咸水环境。 相似文献
108.
The formation and subsequent reactions of magnesiancalcite overgrowths on calcite were investigated bymeans of closed system seeded precipitationexperiments. These experiments demonstrated that(1) thin overgrowths of magnesian calcite are precipitatedon calcite seeds suspended in seawater;(2) the solubilities of the coatings increase outward from theseed crystals as a linear function of the log ofrelative coating thickness;(3) during the period ofthese experiments (up to 5.5 months), the magnesiancalcite coatings continued to increase in thickness,but became less soluble in composition. Thestabilization reaction, referred to asrecrystallization, can be described by the followingequation:Cax Mg(1-x) CO3 + [z + y(x + z)]Ca2++ 2yHCO3- ]= (1 + y)Ca(x + z)Mg(1 - x -z)CO3 + [z + y(x + z - 1)]Mg2++ y CO2 + yH20;]4) recrystallization rate is dependent on solutionsaturation state, with a reaction order of 3.2 forartificial seawater and 4.0 for natural seawater; and(5) by the cessation of the closed system experiments,overgrowth compositions approached that of the stablecalcite (a few mol % MgCO3).Armoring of suspended carbonate particles in thesurface oceans with magnesian calcite overgrowthswould provide an effective barrier to release of theoceanic supersaturation with respect to calcite. Thicknesses of such coatings would be limited by therecrystallization rate of the magnesian calcite. Estimates based on the recrystallization ratesdetermined in this work indicate coatings on the orderof 0.02 µm in thickness could form on particles asthey sink through the mixed layer. According to thesecalculations, the total amount of carbon precipitatedannually in magnesian calcite overgrowths iscomparable to the riverine flux of dissolved carbon tothe oceans. Field observations of severalinvestigators indicate the likely presence ofmagnesian calcite coatings on planktonic particles,and provide evidence for possible recrystallization ofbiogenic magnesian particles in the marineenvironment. 相似文献
109.
海水入侵水化学指标及侵染程度评价研究 总被引:26,自引:1,他引:25
选择Cl^,M、Br^-,rHCO3/rCl及SAR5项水化学要素作为综合判断海水入侵的指标:染程度划分为4级;确定了各项指标入程度的等级范围。入侵程度的衡理采用模糊数学综合判模型。 相似文献
110.
A study on the curves of the exchange ratio E(%)-pH on the liquid-solid interface of the systems Zn(II) with clay minerals (Kaolinite , illite and montmorillonite), Zn(II) with hydrous ferric oxides (amorphous ferric oxide, goethite and hematite). Zn(II) with hydrous manganese oxide (y-MnOOH, manganite and 5-MnO2) etc . in seawater resulted in the discovery of new plateau type exchange ratio ?%)-pH curves not yet reported in literature. The two factors that decide the growth , decline and the change of the " plateau type " curve are : (1) the inherent characteristics of systems , which can be explained by the exchange constants i(i=1 ,2 , 3 . etc .) of interfacial stepwise ion / coordination particle exchange between liquid and solid ; and (2)The theory of interfacial stepwise ion/coordination(the amount of solid exchange reagent)particle exchange in seawater was applied to explain the experimental results of the above study and a general formula was derived for the plateau type exchange ratio E(%)-pH c 相似文献